Do This?

[effone]

In member_profile template; find this:

{$buddy_options}

and make it:

<span id="buddy_options">{$buddy_options}</span>

Now open your global.css and add at the end:

#buddy_options a {
	display: block;
	margin-top: 20px;
}

Or more specifically:

#buddy_options a {
	display: block;
}
#buddy_options > a:nth-child(3), #buddy_options > a:nth-child(4){
	margin-top: 20px;
}

Change the px value of margin-top as you need.